Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532

    • Product Name: Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532
    • Factroy Site: No. 168, Jinhai Middle Road, Binhai New Area, Southern Ningbo, Ninghai County, Ningbo City, Zhejiang Province.
    • Price Inquiry: sales8@bouling-chem.com
    • Manufacturer: Zhejiang Runhe Chemical New Material Co., Ltd.
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    VTB
    Specifications
    HS Code 135193
    Productname Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532
    Productcategory Textile smooth finishing agent
    Appearance Light yellow to yellowish transparent liquid
    Ionicity Weak cationic/nonionic
    Ph 5.0–7.0 (1% aqueous solution)
    Watersolubility Soluble in water
    Solidcontent 30% ± 2%
    Recommendeddosage 10–30 g/L
    Applicationmethod Padding
    Liquidpickup 70%–80%
    Dryingcondition 100–120 °C
    Curingcondition 150–170 °C
    Mainproperty Imparts smooth hand feel and improves surface smoothness
    Applicablefabric Mercerized blended fabrics
    Compatibility Compatible with most conventional finishing agents; pre-test recommended
    Storagestability Stable under sealed normal storage conditions
    Shelflife 6–12 months
    Packaging Plastic drum or IBC container

    As an accredited Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing RH-NB-532 is packaged in 120 kg sealed plastic drums with clear labels for safe industrial handling and transport.
    Container Loading (20′ FCL) Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532 is container-loaded in a 20′ FCL, securely packed for export shipment.
    Shipping Shipping description: Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532 is supplied in sealed plastic drums or IBC totes. Transport in cool, dry, ventilated vehicles; protect from freezing, sunlight, rain, and contamination. Keep containers closed and upright. Classify and label according to SDS and local transport regulations.
    Storage Store Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532 in a cool, dry, well-ventilated warehouse away from direct sunlight, heat, and ignition sources. Keep containers tightly closed, properly labeled, and only in original or compatible containers. Avoid incompatible chemicals and freezing or extreme temperatures. Use secondary containment, stack securely, keep aisles clear, and follow local regulations and SDS recommendations.
    Shelf Life Typically six months in original sealed packaging, stored cool, dry, and ventilated; verify exact shelf life on COA/label.
    Application of Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532

    On continuous finishing ranges for mercerized cotton/polyester woven shirting, RH-NB-532 is applied as an aqueous pad-liquor component after reactive dyeing or continuous dyeing and prior to sanforizing. The fabric entering the pad mangle typically carries residual moisture below 65% and residual alkali below 0.05 g/L; pad-bath pH is therefore adjusted to 5.5–6.5 with acetic acid. At a wet pick-up of 65–75%, a pad-bath addition of 20–40 g/L produces a dry add-on of approximately 1.3–3.0% by fabric weight. The treated substrate is dried at 130–150 °C in the first three stenter zones and cured at 160–170 °C for 45–90 s; over-curing above 180 °C promotes yellowing on polyester-blend whites. Compliance for this class of shirting is verified against GB/T 18401-2010 category B, OEKO-TEX Standard 100 class II, REACH Annex XVII Entry 72, and ZDHC MRSL v3.1. Dimensional stability after finishing is assessed using ISO 6330:2021 procedure 4N at 40 °C, while seam slippage is measured according to ISO 13936-2:2004 at a 100 N load. End products include non-iron men’s and women’s shirts, uniform blouses, and blouse-weight shirting for tailored apparel.

    Batch-to-batch variation in mercerization quality influences the actual surface film distribution of RH-NB-532. When residual sodium carbonate exceeds 0.03 g/L in the fabric, bath pH drifts above 6.5 and edge deposition can occur on ten-chamber pin stenters running above 60 m/min. This edge deposition is not immediately visible at the exit, but after sanforizing it appears as a strip of higher gliss and lower seam friction. On pad mangles fitted with S-rolls, squeeze pressure should be held at 2.5–4.0 bar to avoid pick-up above 75%, which increases drying demand and shifts handle from smooth to resin-like. The agent should not be combined with strong anionic levelling agents or residual peroxide from bleaching; turbidity above 200 NTU in the pad trough indicates incipient incompatibility. Published multi-trial data for this specific product on mercerized polyester-blend shirting is limited; the numerical windows above reflect typical production setpoints on continental stenter lines, not laboratory fabric performance guarantees.

    What Restricts Exhaust Addition on Mercerized Cotton/Modal Jersey to 1.0–2.5% owf?

    For mercerized cotton/modal single jersey intended for next-to-skin apparel, exhaust application after enzyme treatment and dyeing confines RH-NB-532 addition to 1.0–2.5% owf in softflow or overflow jet equipment. Liquor ratio is maintained at 1:8–1:12, bath temperature at 40–50 °C, and treatment time at 15–20 min; the bath is adjusted to 5.5–6.0 before dosing. Above 2.5% owf, the surface coefficient of friction decreases sufficiently to produce overlock seam slippage on high-stretch jersey, which is assessed by marker-yarn displacement after repeated wash cycles rather than by a single tensile test. The finished fabric must satisfy GB/T 18401-2010 category B for adult underwear, OEKO-TEX Standard 100 class II, REACH Annex XVII Entry 72, and the current ZDHC MRSL v3.1 emissions pathway. Pilling resistance is monitored under ISO 12945-2:2020 at 2,000 rubs, and smoothness retention is checked after three cycles of ISO 6330:2021 procedure 4N. End products include T-shirts, polo shirts, shorts, pyjama tops and bottoms, and lightweight loungewear.

    On high-speed softflow machines with liquor throughput above 1,200 L/min, dosing RH-NB-532 too rapidly causes temporary foam accumulation in the overflow reservoir. The agent is therefore metered over 5–10 min through the injection side tank. Because mercerized modal swells more than cotton, residual alkali after pre-treatment is often higher; if bath pH rises above 6.5, the emulsion may deposit on heat-exchanger plates and create batch-to-batch shade variation after the next dyeing lot. For dark reactive-dyed lots, a compatibility check with residual hydrolysed dye at 60 °C is required before the first bulk batch. Garments made from this fabric are typically cut-and-sewn as relaxed jersey, not as fully fashioned knitwear, because the low-friction surface shifts overlock seam behaviour more than sleeve setting.

    Pad-Dry-Cure Conditions Where Hydrophilic Retention Outweighs Hand Modification

    For mercerized cotton/polyester and cotton/lyocell sheeting, RH-NB-532 is applied at 10–25 g/L in the final pad bath on a continuous washing-and-finishing range. Wet pick-up is held at 60–70%, with drying at 120–140 °C and a short cure at 150–160 °C for 30–60 s. The lower addition range is selected because the finish must reduce surface friction without forming a continuous film that impedes moisture regain; capillary rise is checked against the internal specification derived from GB/T 21655.1-2008 or equivalent wicking protocols, although this standard applies to knit fabric and is not a direct test for woven sheeting. Compliance for sheeting is verified against GB/T 18401-2010 category B, OEKO-TEX Standard 100 class II, REACH Annex XVII Entry 72, and ZDHC MRSL v3.1. Pilling and fuzzing are assessed under ISO 12945-2:2020 at 2,000 rubs, and dimensional change under ISO 6330:2021 procedure 4N. End products include flat sheets, fitted sheets, duvet covers, pillowcases, and quilt-back fabric.

    On stenter frames with weft straighteners upstream, excessive initial heat can cause over-drying at selvedges and produce a brittle hand difference between centre and edge. Production audits show that keeping first-zone air temperature below 130 °C and exhaust humidity above 18% reduces this differential. The agent should not be mixed with high-solid acrylic binders at bath solids above 45 g/L; phase separation appears as white deposits on pad rollers after 30 min running. For sheeting that must pass industrial laundry protocols, a repeated-wash check under ISO 15797:2017 at 75 °C with alkali and oxidant is used to confirm that the surface finish does not build up on cotton/lyocell fibres.

    Standard or methodScopeParameter evaluatedProduction checkpoint
    GB/T 18401-2010National general safety technical code for textile productspH, formaldehyde, colour fastnessShirting, sheeting, workwear categories B/C
    OEKO-TEX Standard 100Human-ecological safety of textile articlesResidual chemicals, allergenic disperse dyes, extractable heavy metalsClass II for direct skin contact; class I for infant if applicable
    ZDHC MRSL v3.1Manufacturing restricted substances list for textile and footwear productionInput chemistry exclusionPad-bath formulation and chemical inventory disclosure
    ISO 6330:2021Domestic washing and drying procedures for testingDimensional change, smoothness retentionProcedure 4N, 40 °C
    ISO 13936-2:2004Determination of yarn slippage at a sewn seam in woven fabricsSeam slippage at fixed load100 N load for shirting structures
    ISO 12945-2:2020Pilling resistance by Martindale methodSurface fuzzing and pill formation2,000 rubs on sheeting and knits

    For mercerized cotton/polyester workwear fabric that must survive industrial laundering, RH-NB-532 is applied at 15–30 g/L in a pad bath that often also contains a low-formaldehyde easy-care resin and a magnesium chloride catalyst. The combined bath is buffered to 5.0–6.0; wet pick-up after the pad mangle is controlled at 60–70%. Drying and curing are carried out on a stenter at 150–165 °C for 60–120 s, after which the fabric is sanforized to control residual shrinkage. Tensile strength retention after five industrial wash cycles is measured by ISO 15797:2017 and ISO 13934-1:2013, and seam strength is verified according to ISO 13936-2:2004. The finished fabric is assessed against GB/T 18401-2010 category B or C depending on lining exposure, OEKO-TEX Standard 100 class II, and REACH Annex XVII Entry 72. End products include industrial work shirts, work trousers, boiler suits, and front-panel uniform fabric.

    The main process conflict on workwear lines is not film formation but co-application with resin catalysts. When bath solids exceed 50 g/L or magnesium chloride concentration exceeds 8 g/L, RH-NB-532 can lose emulsion stability and deposit on nip rolls. This deposit is visible as a frosted band on the lower roller and transfers to fabric edges as a greasy streak. Processing with calcium-hard water above 150 mg/L as CaCO₃ accelerates the effect; softened water or demineralized water is required. Because workwear specifications often include higher seam strength than shirting, addition above 30 g/L is not recommended for critical seamed areas; a lower add-on of 15–20 g/L is retained for sleeve seams and crotch seams where high tensile loads occur during wear.

    When Down-Proof Fabric Must Pass AATCC TM 127 Without Sacrificing Surface Slip

    Down-proof mercerized cotton/polyester fabric is a high-density woven substrate with yarn count and cover factor set to prevent feather leakage. RH-NB-532 is applied at 5–15 g/L in the pad bath, a lower window than apparel fabric because the finishing film closes yarn interstices and alters hydrostatic head and air permeability. The fabric is processed through a pad mangle at 50–60% wet pick-up, dried at 120–130 °C, and then calendered at 60–80 °C roll surface temperature with linear pressure between 400–700 N/cm. The finish must allow the calender to compact the weave without causing fibre-to-fibre adhesion that increases tear weakness. Hydrostatic resistance is tested according to AATCC TM 127-2018 and GB/T 12704.1-2009, while tear strength is measured by ISO 13937-2:2000. Compliance includes GB/T 18401-2010 category B, OEKO-TEX Standard 100 class II, and REACH Annex XVII Entry 72. End products include down jacket shells, sleeping bag shells, and down pillow ticking.

    The critical threshold on down-proof lines is the combination of residual finish and calender temperature. If RH-NB-532 add-on exceeds 1.0% dry solids and calender surface temperature exceeds 80 °C, the fabric tends to adhere to steel rolls, producing micro-defects that reduce down-proofness after repeated compression. Conversely, below 5 g/L the shell fabric retains more fibre roughness, and calendering cannot produce uniform interstice closure. Coated down-proof fabric should not receive RH-NB-532 before coating, because the low surface energy film reduces adhesion of polyurethane or acrylic coatings; if a coated shell requires a surface modifier, the finish should be applied after coating and cured below the coating softening point. Published data for this specific configuration is limited, and line trials are required to set calender pressure for each fabric batch.

    Exhaust Application in Garment-Dyed Mercerized Knits and Process-Origin Handling Limits

    Garment-dyed mercerized cotton/polyester knits receive RH-NB-532 during the final exhaust softening step in rotary-drum or high-torque paddle machines. Addition is limited to 1.0–2.0% owf at a liquor ratio of 1:10–1:15, bath temperature 40–50 °C, and running time 15–20 min. The bath is buffered to 5.5–6.0 before the agent is added; direct injection into the drum without buffer causes non-uniform deposition on rib portions and hem folds. After extraction, the garments are tumble-dried at 60–70 °C to fix the finish and restore bulk. Compliance is assessed against GB/T 18401-2010 category B, OEKO-TEX Standard 100 class II, REACH Annex XVII Entry 72, and ZDHC MRSL v3.1. Colour fastness to washing is checked under ISO 105-C06:2010 A2S at 40 °C, and dimensional stability under ISO 6330:2021 procedure 4N. End products include garment-dyed polo shirts, hooded sweatshirts, joggers, and ribbed cuff-and-hem panels.

    In garment-dyed production, the main operational boundary is residual silicone or softener from earlier processes. If the fabric was piece-dyed with a durable antistatic or cationic softener, RH-NB-532 can exhaust incompletely and form a white deposit on drum walls after several cycles. This deposit is removed with a hot acetic acid rinse at 60 °C and pH 4.0–4.5 before the next lot. For dark garments, the finishing agent should be checked for emulsion stability at 50 °C with a sample of the final rinse bath; turbidity above 150 NTU indicates that residual soluble dye has interacted with the emulsion. The process is not recommended for fabric containing un-neutralised alkali above 0.05 g/L because pH drift above 6.5 produces hard handle and uneven surface slip.

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    Certification & Compliance
    More Introduction

    Mercerized Blended Fabric Smooth Finishing Agent RH-NB-532 is supplied as an aqueous, low-amino polyurethane-modified polysiloxane dispersion for continuous pad application on mercerized cotton/polyester and cotton/polyamide blended wovens. The preparation is nonionic/weak cationic and is formulated to reduce inter-fiber friction after stenter finishing while maintaining the dimensional stability produced by mercerization. The product model RH-NB-532 is not a bulk softener; it functions primarily as a surface-smoothing and anti-creasing agent, with a film that is less tacky than conventional amino-functional dimethylsilicone systems. Under the supplier’s REACH declaration, the formulation contains no APEO and no chlorinated solvents.

    In mill practice, the product is used to improve sewability, control handle, and reduce crocking damage on mercerized blended shirting and bottom-weight fabrics. It is introduced after mercerization neutralization and before final drying on a stenter. The following sections describe the specification envelope, process conditions, and operational boundaries for the product; batch-specific certificates of analysis should be consulted for lot acceptance.

    Specification envelope and physical form

    The representative specification envelope for RH-NB-532 is shown below. Values are typical for the product class and should be verified against the supplier’s certificate of analysis before the first production run.

    Representative physicochemical specification envelope for RH-NB-532
    ParameterTypical value/rangeTest method or equipment
    AppearanceMilky white to off-white aqueous dispersionVisual assessment at 25 °C
    Ionic characterNonionic/weak cationicZeta potential +5 to +15 mV at 0.1 % dilution
    pH5.5–6.5ISO 787-9
    Non-volatile content30–35 % by massISO 3251
    Viscosity200–800 mPa·sBrookfield RVT, spindle 2, 20 rpm, 25 °C
    Density1.00–1.05 g/cm³ISO 2811-1
    Dilution waterCold demineralized water preferredConductivity < 50 µS/cm
    Storage stability6 months in sealed containers at 5–35 °CFreeze–thaw cycling not recommended

    In storage, phase separation should not occur; if slight creaming appears after prolonged standing, gentle low-shear stirring is sufficient to restore homogeneity. High-shear reconstitution is not recommended because it can introduce foam and reduce the stabilizing layer thickness. Storage below 5 °C is not recommended because freeze–thaw cycling can break the polyurethane-modified siloxane dispersion. The product shows shear-thinning rheology; viscosity decreases with increasing spindle speed, indicating that the dispersion is not Newtonian. In large pad troughs, continuous recirculation at 10–20 L/min per trough is therefore used to prevent concentration drift in low-shear zones.

    In a continuous pad–dry–cure sequence on mercerized cotton/polyester 65/35 shirting at 110–130 g/m², the start-up concentration of RH-NB-532 is set at 10–15 g/L in demineralized water. The fabric is passed through a pad mangle at 70–80 % wet pickup; lower pickup requires proportional upward adjustment of bath concentration to maintain equivalent add-on. The bath pH is adjusted with acetic acid to 5.0–6.0. Residual alkali from mercerization must be neutralized to a fabric surface pH of 6.0–7.0 before entry. After padding, drying on an 8-chamber stenter at 30–50 m/min with first zones at 120–130 °C and final cure at 150–170 °C for 60–120 s is typical for cellulosic/polyester blends.

    For bottom-weight mercerized cotton/polyester twill at 220–260 g/m², the padding bath concentration is increased to 20–30 g/L. This higher add-on is justified when the fabric is to be cut and sewn on multi-needle post-bed machines running above 4000 stitches/min; lower add-on values may not reduce needle friction sufficiently, and seam pucker can increase. On some production lines, foam generation in the pad trough at the higher concentration is controlled with a polydimethylsiloxane defoamer at 0.1–0.3 g/L.

    Bath preparation is performed by adding RH-NB-532 to cold demineralized water under gentle circulation. High-shear mixing is unnecessary and can produce foam that leads to uneven pickup in the pad trough. The finished bath should be consumed within 24 h at 25 °C without continuous stirring because sedimentation may occur. Where water hardness exceeds 200 mg/L CaCO₃, a chelating agent at 1–2 g/L is added before the finish to stabilize the dispersion.

    On mercerizing ranges fitted with recuperator washing, residual alkali on the entering fabric can vary from 0.1 % to 0.5 % by mass before neutralization. If the neutralization step is shortened to increase line speed, fabric surface pH can drift above 8.0 and destabilize the pad bath. This is a recurrent production-scale failure mode: deposits on the first stenter guide rollers appear within 20–40 min and produce dark streaks on the fabric. The corrective action is to recheck the fabric after the final wash box, not only the pH of the pad bath, and to add dilute acetic acid at the neutralization stage to maintain surface pH 6.0–7.0.

    On wide-width machines above 220 cm, pad roller pressure can vary across the width by more than 5 % if the roller crowns are not correctly maintained. This variation becomes visible as side-to-side handle differences after curing. Mill trials show that a wet pickup variation of ±5 % across the width is enough to shift add-on by 2–3 g/L and alter fabric smoothness. Therefore the pad roller should be checked with pressure-sensitive film before the first production run, and the finish bath should be sampled from left, center, and right pad trough positions.

    What distinguishes RH-NB-532 from conventional amino-silicone softeners and polyethylene wax emulsions?

    The functional difference is the film architecture. Amino-functional silicones orient amine groups onto fiber surfaces and create a bulky, soft handle; however, those amine groups can act as yellowing precursors under dry heat or in the presence of phenolic storage materials. Polyethylene wax emulsions deposit as discrete waxy platelets that reduce fabric-to-metal friction but can increase inter-yarn movement and seam slippage under load. RH-NB-532 combines a low-amino polysiloxane segment with a polyurethane bridging unit. The urethane segments form a coherent low-tack film, while the siloxane chains provide surface smoothness without the greasy handle associated with high-amino fluids.

    Published data for this specific configuration is limited; comparative statements are therefore constrained to bench-scale evaluation on mercerized cotton/polyester 65/35 poplin at 20 g/L add-on using AATCC TM202 for handle and ISO 13936-2 for seam slippage resistance. At equal add-on, the product typically produces a drier handle than an amino-functional silicone and lower seam slippage than a polyethylene wax emulsion. Unlike conventional amino-silicone softeners, RH-NB-532 does not require post-cure washing to control heat-induced yellowing, although whiteness retention should still be confirmed by ISO 105-X18 phenolic yellowing and ISO 105-B02 light fastness on the finished article.

    Compared with a reactive silicone microemulsion, RH-NB-532 has lower crosslinking density after cure; it does not produce the durable elastic handle expected from high-reactive systems. This is a deliberate performance boundary: the product is selected when seam smoothness and dry handle are more important than ultra-high fabric elasticity. Reactive systems may give better after-wash softness but can increase seam slippage and shade change on dark reactive dyes if catalysis is not tightly controlled.

    When applied with low-formaldehyde DMDHEU resin systems, the product shows better co-bath compatibility at low resin concentrations than most amino-silicone macro emulsions; however, jar testing with the specific catalyst and magnesium chloride hexahydrate is required before production because catalyst acidity can alter the bath pH and film formation. Unlike polyethylene wax, the film does not require high temperature for migration; stenter drying at 140–150 °C is sufficient to develop the smooth handle on mercerized lyocell blends.

    When bath pH exceeds 8.5 or anionic co-auxiliaries are present, emulsion stability must be revalidated

    At working bath pH above 8.5, the weak cationic character of the dispersion is progressively neutralized, increasing turbidity and deposition on pad rollers. Anionic wetting agents, sulfonated dye fixatives, or high-phosphate sequestrants can bridge the cationic groups and cause coagulation; their combined use requires jar testing at the intended working concentration and temperature. The product is also incompatible with amine-based formaldehyde-scavenging additives because amine volatiles can shift bath pH and alter film formation. In finishing baths containing optical brighteners or reactive dye acid donors, a preliminary compatibility check over 2–4 h is necessary to detect delayed creaming.

    The product is not intended for garment dyeing after finishing because the film may partially reject dye uptake; if garment dyeing is planned, the finish should be applied after dyeing. On resin-finished goods, free formaldehyde release should be rechecked using ISO 14184-1 after the finish is combined with resin and catalyst, because acidity migration can affect formaldehyde scavenging.

    Because the product is not a bulk softener, add-on above 3.0 % on mass of fabric is generally unnecessary. Excess finish can reduce tear propagation resistance measured by ISO 13937-2 and increase surface deposits on the stenter frame. At add-on above 3.5 %, the film may become visible as a surface haze on dark shades; dark mercerized twill should therefore be checked with a light booth under D65 illumination before production.

    Wash durability of the smooth handle is assessed after 5 laundering cycles by ISO 6330 with line dry or tumble dry as specified by the garment buyer. On mercerized cotton/polyester blends, the polyurethane-modified siloxane film is substantially retained after 5 cycles when evaluated by AATCC TM202; after 10 cycles, surface smoothness decreases, and a touch-up finish may be required if the fabric is to be re-cut or re-sewn.

    In white mercerized shirting, the finish can be co-applied with selected stilbene-based optical brighteners, but jar testing is required because the weak cationic character of the dispersion may reduce brightener efficiency. If a brightener is used, the bath pH should be kept below 7.0 and the bath should be protected from light.

    For lot release on export fabrics, the finished article is tested for tensile strength by ISO 13934-1, tear strength by ISO 13937-2, seam slippage resistance by ISO 13936-2, dimensional stability after 5 home laundering cycles by ISO 6330 and ISO 5077, crocking by ISO 105-X12, and free formaldehyde by ISO 14184-1. The formulation is positioned for ZDHC MRSL and OEKO-TEX Standard 100 compliance when used at the recommended add-on; verification by lot-specific third-party testing is required for restricted substances under REACH and RoHS.