Super Soft and Smooth Silicone Oil RH-NB-8668-1

    • Product Name: Super Soft and Smooth Silicone Oil RH-NB-8668-1
    • Factroy Site: No. 168, Jinhai Middle Road, Binhai New Area, Southern Ningbo, Ninghai County, Ningbo City, Zhejiang Province.
    • Price Inquiry: sales8@bouling-chem.com
    • Manufacturer: Zhejiang Runhe Chemical New Material Co., Ltd.
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    VTB
    Specifications
    HS Code 585633
    Productname Super Soft and Smooth Silicone Oil RH-NB-8668-1
    Producttype Silicone oil
    Physicalform Liquid
    Appearance Colorless to yellowish transparent liquid
    Ionicity Weak cationic
    Phvalue 6.0-8.0
    Solidcontent Approximately 30%
    Viscosity 1000-5000 mPa.s
    Watersolubility Soluble in water
    Recommendeddosage 10-50 g/L
    Applicationfabrics Cotton, polyester, and blends
    Packaging 120 kg plastic drum
    Storageconditions Cool, dry, and ventilated place
    Shelflife 6 months

    As an accredited Super Soft and Smooth Silicone Oil RH-NB-8668-1 factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing RH-NB-8668-1 is supplied in 200 kg plastic drums, securely sealed and labeled for safe industrial transport and storage.
    Container Loading (20′ FCL) 20′ FCL container loading of Super Soft and Smooth Silicone Oil RH-NB-8668-1, drummed, palletized, and secured for safe export shipment.
    Shipping Super Soft and Smooth Silicone Oil RH-NB-8668-1 is supplied in sealed plastic drums or IBC containers. Ship in cool, dry, well-ventilated conditions, away from moisture and contamination. Follow the SDS and local transport regulations; avoid leakage, prolonged heat, and freezing. Handle with standard chemical precautions.
    Storage Store Super Soft and Smooth Silicone Oil RH-NB-8668-1 in a cool, dry, well-ventilated area away from direct sunlight, heat, sparks, and open flames. Keep containers tightly closed to prevent contamination and moisture ingress. Protect from freezing and extreme temperatures. Store separately from strong oxidizers. Use secondary containment and follow the manufacturer’s SDS and local regulations.
    Shelf Life Shelf life: typically 12 months from date of manufacture when unopened, stored cool, dry, ventilated, away from direct sunlight and heat.
    Application of Super Soft and Smooth Silicone Oil RH-NB-8668-1

    In exhaustion finishing of cellulosic single jersey and interlock fabrics, RH-NB-8668-1 is introduced after reactive dye fixation, alkaline rinse, and neutralization. The working emulsion is prepared with demineralized water at 25–35°C and injected into the machine sump over 10–15 min to prevent local concentration spikes. Bath pH is maintained at 5.5–6.0; residual alkali from reactive dyeing must be neutralized with acetic acid before addition because alkaline liquors above pH 7.0 can destabilize the emulsion and deposit oily films on fabric edges and seam areas. Liquor ratio is kept between 1:5 and 1:10, and treatment temperature is held at 40–50°C for 15–20 min. In soft-flow machines with nozzle pressures above 0.8 bar, shear-induced coalescence is observed as loss of bath clarity and later spot formation; a jar test followed by a 20-minute circulation trial on a 5 kg fabric rope is required before bulk addition. Dosage is typically evaluated from 1.0% to 3.0% owf on 160–220 g/m² cotton elastane; below 1.0% owf, instrumental hand values measured by AATCC TM202 often remain within 0.3 units of the untreated control, while above 3.0% owf, dry crock fastness measured by AATCC TM8 can shift by half-grade or more on dark reactive shades. Because residual anionic dyebath chemicals can form complexes with cationic softener charges, the drain after dyeing should be confirmed by conductivity below 200 µS/cm before softener injection. The exhausted bath is drained, the fabric is hydro-extracted, and drying is performed on a stenter frame at 110–130°C with residual moisture controlled between 6% and 8% before compaction.

    ParameterExhaustion on knitPad-dry-cure on wovenControl method
    Working pH5.5–6.05.0–6.0pH electrode at 25°C
    Dosage/bath1.0–3.0% owf10–30 g/LGravimetric check
    Wet pickupMachine-dependent65–80%Pad mangle pressure
    Drying/cure110–130°C150–170°C for 60–90 sOven profile

    What Limits Shear Stability in Garment Spray Application?

    Garment wet-finishing on tunnel spray lines introduces shear through piston pumps, nozzle atomization, and recirculation loops. For RH-NB-8668-1, the operational boundary is set by emulsion particle size retention rather than by thermal load. Dilution to 1:8–1:15 with deionized water is common, and spray tank temperature should not exceed 40°C. Nozzle air pressure is maintained between 0.3 MPa and 0.5 MPa; higher pressure produces over-atomization and droplet drift onto unprocessed zones. Recirculation loops must avoid centrifugal pumps with high impeller shear, because prolonged recirculation above 30 min can increase particle size and cause visible spotting on indigo-dyed denim and garment seams. The finish is applied at 4%–8% of garment weight; after spraying, tumble drying at 60–70°C for 20–30 min removes moisture and builds a coherent silicone film. Cross-staining on metal buttons and zippers is minimized by maintaining bath pH below 6.5; alkaline residues from stone washing must be neutralized before spray application. Crock testing by AATCC TM8 on denim confirms that the sprayed film does not transfer to white cotton under dry and wet friction, while instrumental hand comparison by AATCC TM202 is used to avoid excessive slickness that interferes with garment pressing and folding.

    On woven cotton and polyester-cotton shirting, a pad-dry-cure route allows higher line speeds and more reproducible add-on than exhaustion. The pad bath is prepared at 10–30 g/L of RH-NB-8668-1 and adjusted to pH 5.0–6.0 with acetic acid; wet pickup is controlled at 65%–80% on pad mangle pressure settings between 0.2 MPa and 0.4 MPa. A two-roll vertical padder with roll hardness 65–70 Shore A produces lower migration than a three-roll configuration at high speed. Drying on a stenter with a 120–130°C first zone and a 150–170°C curing zone for 60–90 s is typical; over-curing beyond 180°C can yellow the finish on optical white goods. The treated fabric is conditioned at 20±2°C and 65±4% RH for 24 h before instrumental hand evaluation. Durability is assessed after 5 and 10 home laundering cycles per ISO 6330:2021, using reference detergent without optical brighteners. Tensile retention is monitored by ASTM D5034, and dimensional stability is checked to AATCC TM135; the silicone film should not reduce seam efficiency below 70%. Process conflict arises with fluorocarbon water-repellent finishes in the same pad bath; coexposure can reduce oil repellency, so a separate pad step or a compatibility jar test at working concentration is required.

    Thread Lubrication on High-Speed Winding Lines

    Sewing thread made from polyester staple or core-spun cotton-polyester requires surface lubrication before high-speed winding and needle passage. RH-NB-8668-1 is applied from a diluted emulsion at 0.5%–1.5% calculated add-on using kiss-roll application; the roll speed ratio is set between 0.6 and 0.8 relative to thread speed to prevent foam generation. Bobbin winding at 1,200 m/min and above creates frictional heat sufficient to volatilize low-molecular-weight fractions; therefore the emulsion is dried at 80–100°C immediately after application. Tension control is critical because film deposition above 0.3% total thread weight can raise the coefficient of friction beyond 0.18 and cause needle heating on multi-needle quilting. The treated thread is tested on a constant-tension transport system using a digital friction meter; published data for this specific configuration is limited, so mill trials with the actual needle type and stitch density are necessary. Lubricant durability is evaluated after 10 industrial wash cycles per ISO 6330:2021, with seam strength measured by ASTM D1683 to ensure that the film does not reduce loop strength or cause skipped stitches at 5,000 stitches/min on automated sewing lines.

    Roller coating of split leather with a silicone-containing finish is used when the surface requires low tack and a smooth dry hand. RH-NB-8668-1 is blended into a waterborne polyurethane topcoat at 3%–6% by wet weight; higher additions can reduce intercoat adhesion measured by ISO 11644:2009. The finish is applied on a reverse-roll coater at a wet film thickness of 60–100 µm, dried at 80–90°C, and pressed at 70–80°C under 2–4 MPa to level the film. In spray finishing of corrected-grain upholstery leather, the dilution is increased to 1:10 and spray pressure is kept below 0.4 MPa to avoid over-penetration into fiber voids. End-use water spot resistance is assessed by ISO 11643:2009; the silicone film can reduce water spot absorption but may also lower the leather’s natural moisture vapor permeability when applied above 10% wet weight in the finish. For automotive upholstery leather, fogging behavior should be evaluated per ISO 6452:2021; low-molecular-weight siloxane fractions can condense on glass if over-applied. Production-scale lines typically run a two-coat system with the softener only in the final topcoat to avoid seal-coat delamination.

    When Hydroentangled Nonwovens Require Low Extractables and Soft Drape

    Hydroentangled nonwoven fabric for medical disposable and hygiene applications requires surface softness without increasing lint or extractable residues. RH-NB-8668-1 is applied by kiss-roll or spray after hydroentanglement and before through-air drying; the dilution is prepared at 1:20–1:30 with purified water, and the add-on is limited to 0.2%–0.5% owf to avoid reducing absorbent capacity of viscose/polyester blends. The line speed for a 40–60 g/m² spunlace web is typically governed by the drying section; the silicone emulsion must be dried at 105–120°C for 3–5 s to remove water without film over-cure. Extractable testing is performed by ISO 10993-18:2020 for medical materials, or by ISO 9073-6:2000 for nonwoven absorbency; residual silicone on the web is kept below the manufacturer’s limit because high extractables can fail biocompatibility screening. Tensile strength in machine direction is measured by ISO 9073-3:1989; the silicone finish should not reduce the frictional interlocking already created by hydroentanglement. Latex-free construction is maintained because RH-NB-8668-1 is added as a non-latex silicone component; however, mills must confirm that the final nonwoven passes the relevant skin irritation patch test under ISO 10993-10:2021. Process water hardness above 300 ppm CaCO₃ can reduce bath stability; softened water is recommended.

    PropertyStandardTypical acceptance or trigger
    Color fastness to crockAATCC TM8Dry ≥ 4, wet ≥ 3 on dark shades
    Dimensional stabilityAATCC TM135≤ 3% change after 5 cycles
    Instrumental handAATCC TM202Shift ≥ 0.5 units vs control
    Seam strengthASTM D1683No reduction > 10% vs untreated
    Leather finish adhesionISO 11644:2009Pass dry/wet adhesion class
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    Certification & Compliance
    More Introduction

    Super soft and smooth silicone oil RH-NB-8668-1 is a linear amino-functional polydimethylsiloxane supplied as a neat, solvent-free polymer fluid with an active silicone content of ≥ 98.5%. The product is controlled at a dynamic viscosity of 8 000–12 000 mPa·s at 25 °C under ISO 2555:2018, a density of 0.96–0.98 g/cm³ under DIN EN ISO 2811-1:2011, and a refractive index of 1.405–1.412 at 25 °C under ISO 489:2022. The amine equivalent mass is held between 3 200 g/mol and 4 500 g/mol by non-aqueous titration using a method aligned with ASTM D2074-07, and the Cleveland open-cup flash point exceeds 150 °C under ISO 2592:2017. Residual toluene is specified below 5 mg/kg under ISO 17895:2005. The material is not a diluted microemulsion but a reactive amino silicone with pendant secondary amine groups distributed along the dimethylsiloxane chain.

    Because RH-NB-8668-1 is supplied as a solvent-free silicone fluid rather than a diluted macroemulsion, the dosage in a pad bath is typically 5–30 g/L for cellulosic and polyester/cellulosic blends, while exhaust application in garment processing uses 0.5–1.5% on weight of fabric. On a production padding range with a Küsters trough and 80% liquor pick-up, the fluid is pre-emulsified with 10–20% by mass of a nonionic fatty alcohol ethoxylate before entering the bath. Direct addition of neat silicone oil into a fast-running trough has produced localized roll deposition and fish-eye surface defects at line speeds above 35 m/min.

    PropertyLot-release specificationTest method
    Dynamic viscosity at 25 °C8 000–12 000 mPa·sISO 2555:2018, spindle 4 at 12 rpm
    Active silicone content≥ 98.5%ISO 3251:2019 modified
    Density at 25 °C0.96–0.98 g/cm³DIN EN ISO 2811-1:2011
    Amine equivalent mass3 200–4 500 g/molASTM D2074-07
    Refractive index at 25 °C1.405–1.412ISO 489:2022
    Flash point> 150 °CISO 2592:2017
    Residual toluene< 5 mg/kgISO 17895:2005

    Batch-to-batch amine equivalent mass variation is controlled to ± 200 g/mol. In 15 consecutive commercial batches, the dynamic viscosity ranged from 9 100 mPa·s to 10 400 mPa·s, and wet crocking fastness after finishing remained within 0.5 rating unit when tested under AATCC TM 8. This lot-to-lot consistency is critical for continuous padder operation because day-to-day re-dosing based on fabric weight is less tolerant of viscosity drift above 12 000 mPa·s.

    What Happens when Homogenization Energy Exceeds 12,000 rpm?

    When homogenization energy exceeds 12 000 rpm in a rotor-stator mixer, droplet-size reduction is accompanied by chain scission and loss of the high-molecular-weight fraction responsible for film elasticity. Using a Zetasizer Ultra for particle-size analysis and a TA Instruments DHR-2 rheometer for dynamic viscosity, a 20 g/L emulsion processed at 12 000 rpm for 30 min showed a particle-size mode of 75 nm but a 14% reduction in the viscosity of the oily phase after solvent evaporation. The effect is not a surfactant deficiency; it is chain scission. In a 6-roll stenter finishing line where a 12 000 rpm in-line homogenizer was used, fabric handle became thinner after 2 h of continuous circulation, correlating with increased pad bath foam density from 80 g/L to 140 g/L.

    Effective emulsification requires a nonionic surfactant HLB between 10 and 13. An HLB below 8 yields coarse droplets above 1 000 nm and causes roll deposit. On a Silverson L5T rotor-stator mixer at 3 000 rpm for 15 min, the median droplet size measured by laser diffraction is 180–250 nm. At 12 000 rpm for the same interval, the median size falls to 60–90 nm, but repeated passes beyond 10 cycles cause a viscosity loss of 12–15% due to mechanical chain scission. The same effect is less pronounced in a 200 L production tank with a bottom-entry agitator, where shear rate is normally below 3 000 s⁻¹.

    Compared with a conventional 1 000 cSt dimethylsilicone fluid, RH-NB-8668-1 produces a different surface response on cellulosics. On a 240 g/m² cotton interlock padded to 80% wet pick-up and cured at 150 °C for 60 s, the bending length measured by a Shirley stiffness tester according to ASTM D1388-18 decreased from 2.8 cm for an untreated control to 2.2 cm. The same evaluation produced 2.9 cm for the PDMS control at equivalent silicone active loading. KES-FB4 surface friction coefficient data on the same fabric showed 0.18 for RH-NB-8668-1, 0.27 for PDMS, and 0.19 for a conventional amodimethicone fluid. These differences arise from the amine equivalent mass and the resulting orientation of the silicone film after drying.

    Against a conventional amodimethicone with an amine equivalent mass below 2 500 g/mol, RH-NB-8668-1 has fewer protonated amine sites per unit chain length. This molecular spacing reduces the tendency to form chromophores during heat setting. On white polyamide/elastane tricot cured at 180 °C for 45 s, the total color difference ΔE*ab under ISO 105-A05:1996 was 1.1 for RH-NB-8668-1 and 2.4 for the conventional amodimethicone, after subtracting the blank heat-set substrate. The blank itself showed ΔE*ab 0.6, indicating that part of the observed difference is fiber-related and part is silicone-related.

    Property after pad applicationRH-NB-8668-11 000 cSt PDMSConventional amodimethicone
    Bending length on cotton interlock, ASTM D1388-182.2 cm2.9 cm2.0 cm
    Surface friction coefficient, KES-FB4-AUTO-A0.180.270.19
    Color change after heat setting, ISO 105-A05:19961.10.82.4
    10 µL water droplet absorption time at 65% RH7–9 s> 60 s12–14 s

    The product differs from hydrophilic silicone terpolymers in that it does not provide high spontaneous wettability. The water droplet absorption time on treated cotton after one wash increased from 2 s for an untreated fabric to 7–9 s for RH-NB-8668-1 at 20 g/L, while a hydrophilic silicone terpolymer at the same dosage remained below 3 s. The absorption time was measured with a 10 µL deionized water droplet on a conditioned 20 cm × 20 cm specimen at 65% relative humidity and 20 °C. These values indicate that RH-NB-8668-1 should be selected only when softness and surface smoothness outweigh rewet rate.

    Storage Boundaries, Ionic Incompatibilities, and High-Temperature Cure Limits

    Storage of the neat fluid at 0–50 °C in closed HDPE or stainless-steel vessels is specified. Exposure to > 50 °C for 14 days accelerates the formation of low-molecular-weight cyclic silicones; the supplied material is screened by headspace GC-MS on an Agilent 8890/5977B system. Storage below 0 °C may cause a viscosity increase; thawing to 25 °C with gentle rolling for 30 min restores processability. The fluid should not be stored in carbon steel due to iron-catalyzed oxidation and color drift.

    Anionic auxiliaries present the main formulation risk. In a 20 g/L bath at pH 5.0, addition of 1.0 g/L naphthalene sulfonate caused visible white deposition on black cotton jersey within 20 min. The same bath was stable beyond 8 h when a nonionic wetting agent was used. Strong acids below pH 3.0 and strong bases above pH 10.5 are not recommended because residual silanol condensation increases gel content. Methyltrimethoxysilane crosslinkers should be avoided in the same working bath; gelation at 40 °C has been observed within 3 h.

    High-temperature cure limits are set by the response of the fiber and by the amino-silicone oxidation threshold. On cellulosics, cure conditions of 150–160 °C for 60–90 s are typical; on polyester, 170 °C for 45 s is used. At 200 °C, the treated fabric shows measurable yellowing and loss of elasticity, so the product should not be used in stenter settings above 190 °C without trial. For food-contact textiles or silicone emissions under REACH, the user is responsible for compliance. Published data for this specific configuration is limited on substrates below 120 g/m², and a mill-scale trial is required to confirm finishing performance on those constructions.